Electronic Structure of Cobalt-Corrole-Pyridine Complexes : Noninnocent Five-Coordinate Co(II) Corrole-Radical States

Two sets of complexes of Co-triarylcorrole-bispyridine complexes, Co[TpXPC](py)2 and Co[Br8TpXPC](py)2 have been synthesized, where TpXPC refers to a meso-tris(para-X-phenyl)corrole ligand with X = CF3, H, Me, and OMe and Br8TpXPC to the corresponding β-octabrominated ligand. The axial pyridines in...

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Bibliographic Details
Published in:The journal of physical chemistry. A, Vol. 121, No. 50 (2017), p. 9589-9598
Main Author: Ganguly, Sumit
Other Involved Persons: Conradie, Jeanet ; Bendix, Jesper ; Gagnon, Kevin J ; McCormick, Laura J ; Ghosh, Abhik
Format: electronic Article
Language:English
ISSN:1520-5215
Item Description:Date Completed 05.03.2018
Date Revised 05.03.2018
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
Copyright: From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
Physical Description:Online-Ressource
DOI:10.1021/acs.jpca.7b09440
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Published in: The journal of physical chemistry. A, Vol. 121, No. 50 (2017), p. 9589-9598

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Volltext