Photochemistry of β,γ-unsaturated 5,10-seco-steroidal ketones

UV irradiation of the β,γ-unsaturated 5,10-seco-steroidal ketones 1 and 2 in dioxane or isopropanol resulted in Z/E isomerization, while similar irradiation in acetone effected, besides, epoxidation (in the presence of air) and addition of solvent to the olefinic double bond.

Bibliographic Details
Published in:Tetrahedron Letters, Vol. 25, No. 10 (1984), p. 1091-1094
Other Involved Persons: Lorenc, L. ; Pavlovic, V. ; Mihailovic, M.L.
Format: electronic Article
Item Description:Copyright: Copyright (c) 2002 Elsevier Science Ltd
Physical Description:Online-Ressource
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