1,5-Shift of hydrogen from carbon to carbon in the lead tetraacetate oxidation of 5,5-dimethyl-2-heptanol
By using α-deuteriated substrate, it was established that in the thermal lead tetraacetate reaction (in benzene) of 5,5-dimethyl-2-heptanol (1) oxidation to the corresponding ketone 4 proceeds not only by way of direct elimination of the carbinol (α) hydrogen, but also, to the extent of 43.-5%, by a...
|Published in:||Tetrahedron, Vol. 29, No. 22 (1973), p. 3547-3551|
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|Item Description:||Copyright: Copyright (c) 2002 Elsevier Science Ltd|
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