1,5-Shift of hydrogen from carbon to carbon in the lead tetraacetate oxidation of 5,5-dimethyl-2-heptanol

By using α-deuteriated substrate, it was established that in the thermal lead tetraacetate reaction (in benzene) of 5,5-dimethyl-2-heptanol (1) oxidation to the corresponding ketone 4 proceeds not only by way of direct elimination of the carbinol (α) hydrogen, but also, to the extent of 43.-5%, by a...

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Bibliographic Details
Published in:Tetrahedron, Vol. 29, No. 22 (1973), p. 3547-3551
Other Involved Persons: Milosavljevic, S. ; Jeremic, D. ; Mihailovic, M.L.
Format: electronic Article
Item Description:Copyright: Copyright (c) 2002 Elsevier Science Ltd
Physical Description:Online-Ressource
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